Catalysis

Polymerization

Photochemistry

Embedded system

Palladium

Radical cyclization

Computer science

Polymer

Medicinal chemistry

Hydrogen

Organic chemistry

Hydrogen atom

Atom (system on chip)

Chemistry

Atom-transfer radical-polymerization

Group (periodic table)

Angewandte Chemie International Edition

A novel mild, visible-light-induced palladium-catalyzed hydrogen atom translocation/atom-transfer radical cyclization (HAT/ATRC) cascade has been developed. This protocol involves a 1,5-HAT process of previously unknown hybrid vinyl palladium radical intermediates, thus leading to iodomethyl carbo- and heterocyclic structures.

Palladium‐Catalyzed Atom‐Transfer Radical Cyclization at Remote Unactivated C(sp<sup>3</sup>)−H Sites: Hydrogen‐Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates

Palladium‐Catalyzed Atom‐Transfer Radical Cyclization at Remote Unactivated C(sp3)−H Sites: Hydrogen‐Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates

Palladium‐Catalyzed Atom‐Transfer Radical Cyclization at Remote Unactivated C(sp³)−H Sites: Hydrogen‐Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates