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Original paper

Experimental and Computational Development of a Conformationally Flexible Template for the meta-C–H Functionalization of Benzoic Acids

Volume: 139, Issue: 31, Pages: 10702 - 10714
Published: Jul 27, 2017
Abstract
A conformationally flexible template for the meta-C-H olefination of benzoic acids was designed through both experimental and computational efforts. The newly designed template favors a silver-palladium heterodimer low barrier transition state, and demonstrates that it is feasible to lengthen templates so as to achieve meta-selectivity when the distance between the functional handle of the native substrate and target C-H bond decreases. Analysis...
Paper Details
Title
Experimental and Computational Development of a Conformationally Flexible Template for the meta-C–H Functionalization of Benzoic Acids
Published Date
Jul 27, 2017
Volume
139
Issue
31
Pages
10702 - 10714
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