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Original paper

A Stable Silylene with a σ2, π- Butadiene Ligand

Volume: 139, Issue: 20, Pages: 7117 - 7123
Published: May 3, 2017
Abstract
The synthesis of a new type of silylene 1 is reported. It adopts a bicyclo[2.1.1]hexene structure in which a hafnocene group is incorporated. The silylene is stabilized by homoconjugation with the remote C═C double bond. This is indicated by its highly shielded 29Si NMR chemical shift (δ29Si = −155) and is firmly established by its experimental molecular structure from XRD analysis. The results of a detailed bonding analysis based on DFT...
Paper Details
Title
A Stable Silylene with a σ2, π- Butadiene Ligand
Published Date
May 3, 2017
Volume
139
Issue
20
Pages
7117 - 7123
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