Determination of the Cu(III)–OH Bond Distance by Resonance Raman Spectroscopy Using a Normalized Version of Badger’s Rule

Volume: 139, Issue: 12, Pages: 4477 - 4485
Published: Mar 20, 2017
Abstract
The stretching frequency, ν(Cu–O), of the [CuOH]2+ core in the complexes LCuOH (L = N,N′-bis(2,6-diisopropyl-4-R-phenyl)pyridine-2,6-dicarboxamide, R = H or NO2, or N,N′-bis(2,6-diisopropylphenyl)-1-methylpiperidine-2,6-dicarboxamide) was determined to be ∼630 cm–1 by resonance Raman spectroscopy and verified by isotopic labeling. In efforts to use Badger’s rule to estimate the bond distance corresponding to ν(Cu–O), a modified version of the...
Paper Details
Title
Determination of the Cu(III)–OH Bond Distance by Resonance Raman Spectroscopy Using a Normalized Version of Badger’s Rule
Published Date
Mar 20, 2017
Volume
139
Issue
12
Pages
4477 - 4485
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