Original paper
(Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed Direct Trifluoromethylthiolation of Arenes via C−H Activation
Abstract
The direct trifluoromethylthiolation of arenes was realized via (pentamethylcyclopentadienyl)cobalt(III)‐catalyzed C(sp 2 )‐H activation and coupling with AgSCF 3 under the assistance of a directing group. The reaction features redox‐neutrality, mild conditions, broad substrate scope, and good functional group tolerance. Preliminary mechanistic studies have been conducted. magnified...
Paper Details
Title
(Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed Direct Trifluoromethylthiolation of Arenes via C−H Activation
Published Date
Mar 15, 2017
Volume
359
Issue
11
Pages
1942 - 1946