An Investigation of the Selective Chain Scission at Centered Diels–Alder Mechanophore under Ultrasonication

Volume: 50, Issue: 4, Pages: 1353 - 1361
Published: Feb 9, 2017
Abstract
It is a challenging topic to disconnect a linear polymer selectively at the mechanophore site by an external force in a “cold” fashion. In this work, the effect of the power output of ultrasonication on the selective cleavage at the centered urfuryl-maleimide Diels–Alder (DA) mechanophore of poly(methyl acrylate)s (DA-PMA-a and DA-PMA-b) were quantitatively investigated by comparative study on experimental and simulated chain scission kinetics...
Paper Details
Title
An Investigation of the Selective Chain Scission at Centered Diels–Alder Mechanophore under Ultrasonication
Published Date
Feb 9, 2017
Volume
50
Issue
4
Pages
1353 - 1361
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