One pot synthesis of α-ketoamides from ethylarenes and amines: a metal free difunctionalization strategy
Abstract
One-pot and metal free synthesis of α-ketoamides has been described through in situ generation of aryl ketones from easily available ethylarenes followed by amidation with various amines. This multiple oxidation protocol involves catalytic I2-pyridine-TBHP (t-butyl hydroperoxide) mediated oxidative benzylic carbonylation and sequential NaI-TBHP mediated oxidative amidation without using any...
Paper Details
Title
One pot synthesis of α-ketoamides from ethylarenes and amines: a metal free difunctionalization strategy
Published Date
Jan 1, 2016
Volume
14
Issue
48
Pages
11446 - 11453
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