Water-Induced Structural Changes in Crown Ethers from Broadband Rotational Spectroscopy

Volume: 7, Issue: 20, Pages: 4053 - 4058
Published: Sep 30, 2016
Abstract
The complexes of 12-crown-4 ether (12C4) with water, generated in a supersonic jet, have been studied using broadband Fourier transform microwave spectroscopy. Three 1:1 and one 1:2 clusters have been observed and their structures unambiguously identified through the observation of isotopologue spectra. The structures of the clusters are based on networks of O–H···O and C–H···O hydrogen bonds. The most abundant 1:1 cluster is formed from the...
Paper Details
Title
Water-Induced Structural Changes in Crown Ethers from Broadband Rotational Spectroscopy
Published Date
Sep 30, 2016
Volume
7
Issue
20
Pages
4053 - 4058
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