Thermodynamics and selectivity of separation based on activity coefficients at infinite dilution of various solutes in 1-allyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide ionic liquid

The effect of interaction between organic solvents or water on the interfacial and bulk properties of 1-allyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide ([AMIM][NTf2]) and on activity coefficients (γ13∞) at infinite dilution for 64 solutes. The observations monitored by gas-liquid chromatography at six temperatures in range of (318.15–368.15) K are explained for polar and non-polar solutes as alkanes, alkenes and alkynes as well as...