Mechanism of H2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides

Volume: 138, Issue: 29, Pages: 9234 - 9245
Published: Jul 18, 2016
Abstract
The intermediacy of a reduced nickel–iron hydride in hydrogen evolution catalyzed by Ni–Fe complexes was verified experimentally and computationally. In addition to catalyzing hydrogen evolution, the highly basic and bulky (dppv)Ni(μ-pdt)Fe(CO)(dppv) ([1]0; dppv = cis-C2H2(PPh2)2) and its hydride derivatives have yielded to detailed characterization in terms of spectroscopy, bonding, and reactivity. The protonation of [1]0 initially produces...
Paper Details
Title
Mechanism of H2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides
Published Date
Jul 18, 2016
Volume
138
Issue
29
Pages
9234 - 9245
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