Original paper
Reduced Glass Transition Temperatures in Thin Polymer Films: Surface Effect or Artifact?
Abstract
We have examined the direct effect of manipulating the number of free surfaces on the measured glass transition temperature {T}_{\mathrm{g}}of thin polystyrene films. Thin films in the range 35\text{ }\text{ }\mathrm{nm}<h<114\text{ }\text{ }\mathrm{nm}with molecular weights of 592\text{ }\text{ }\mathrm{kg}/\mathrm{mol}and 1144\text{ }\text{ }\mathrm{kg}/\mathrm{mol}were studied. Ellipsometry was used to determine the...
Paper Details
Title
Reduced Glass Transition Temperatures in Thin Polymer Films: Surface Effect or Artifact?
Published Date
Aug 3, 2012
Journal
Volume
109
Issue
5
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Notes
History