Intermolecular Oxidative C–N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp2 and Benzylic sp3 C–H Bond Imidation

Volume: 133, Issue: 41, Pages: 16382 - 16385
Published: Sep 26, 2011
Abstract
A new synthetic approach toward intermolecular oxidative C–N bond formation of arenes has been developed under transition-metal-free conditions. Complete control of chemoselectivity between aryl sp2 and benzylic sp3 C–H bond imidation was achieved by the choice of nitrogen sources, representatively being phthalimide and dibenzenesulfonimide,...
Paper Details
Title
Intermolecular Oxidative C–N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp2 and Benzylic sp3 C–H Bond Imidation
Published Date
Sep 26, 2011
Volume
133
Issue
41
Pages
16382 - 16385
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