Review paper
Global optimization algorithms to compute thermodynamic equilibria in large complex systems with performance considerations
Abstract
Several global optimization methods are reviewed that attempt to ensure that the integral Gibbs energy of a closed isothermal isobaric system is a global minimum to satisfy the necessary and sufficient conditions for thermodynamic equilibrium. In particular, the integral Gibbs energy function of a multi-component system containing non-ideal phases may be highly non-linear and non-convex, which makes finding a global minimum a challenge....
Paper Details
Title
Global optimization algorithms to compute thermodynamic equilibria in large complex systems with performance considerations
Published Date
Jun 1, 2016
Volume
118
Pages
87 - 96
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