Original paper
N-Heterocyclic Carbene-Pd Polymers as Reusable Precatalysts for Cyanation and Ullmann Homocoupling of Aryl Halides: The Role of Solvent in Product Distribution
Abstract
A main‐chain N‐heterocyclic carbene (NHC) polymer with N ‐dodecyl‐substituted groups was found to be a highly efficient precatalyst for cyanation of various aryl halides by using nontoxic cyanic source [K 4 Fe(CN) 6 ] under relatively mild reaction conditions. Several aryl iodides, bromides, and activated chlorides were successfully converted to their corresponding benzonitrile derivatives without using additives (such as reducing agents or...
Paper Details
Title
N-Heterocyclic Carbene-Pd Polymers as Reusable Precatalysts for Cyanation and Ullmann Homocoupling of Aryl Halides: The Role of Solvent in Product Distribution
Published Date
Jul 1, 2015
Journal
Volume
7
Issue
14
Pages
2248 - 2254
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Notes
History