Original paper
Barrier oxide chemistry and hydrogen pick-up mechanisms in zirconium alloys
Abstract
The chemistry of barrier oxide layers formed on zirconium alloys was investigated using atom probe tomography (APT). Grain boundary segregation of Fe and Ni was observed. The Zr(Fe, Cr)2 particles maintain a constant Zr:Fe:Cr ratio through the oxide until they reach an oxygen content of approximately 50 at%, when Fe depletion occurs. Enrichment of hydrogen along oxide crystallite boundaries was observed, which is interpreted as a sign of ingress...
Paper Details
Title
Barrier oxide chemistry and hydrogen pick-up mechanisms in zirconium alloys
Published Date
Jan 1, 2016
Journal
Volume
102
Pages
490 - 502
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Notes
History