Original paper
Retro-aldol-type fragmentation of reducing sugars preferentially occurring in polyether at high temperature: Role of the ether oxygen as a base catalyst
Abstract
The pyrolysis behavior of reducing monosaccharides was compared in the presence and absence of tetraethyleneglycol dimethylether (TEGDE), a polyether (N2/150–250 °C). The pyrolytic pathways changed drastically in TEGDE. Glucose started to decompose at >160 °C under the neat conditions, and polysaccharides, anhydrosugars (levoglucosan and 1,6-anhydroglucofuranose), a colored substance and char were the major products. However, glucose was...
Paper Details
Title
Retro-aldol-type fragmentation of reducing sugars preferentially occurring in polyether at high temperature: Role of the ether oxygen as a base catalyst
Published Date
Jan 1, 2012
Volume
93
Pages
24 - 32
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Notes
History