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doi.org/10.1021/ma500042f

Synthesis of Highly Reactive Polyisobutylene Catalyzed by EtAlCl2/Bis(2-chloroethyl) Ether Soluble Complex in Hexanes

..., Rudolf Faust
35
Macromolecules5.50
Volume: 47, Issue: 6, Pages: 1959 - 1965
Published: Mar 10, 2014
Abstract
The polymerization of isobutylene (IB) to yield highly reactive polyisobutylene (HR PIB) with high exo-olefin content using GaCl3 or FeCl3·diisopropyl ether complexes has been previously reported.1 In an effort to further improve polymerization rates and exo-olefin content, we have studied ethylaluminum dichloride (EADC) complexes with diisopropyl ether, 2-chloroethyl ethyl ether (CEEE), and bis(2-chloroethyl) ether (CEE) as catalysts in...
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Paper Details
Title
Synthesis of Highly Reactive Polyisobutylene Catalyzed by EtAlCl2/Bis(2-chloroethyl) Ether Soluble Complex in Hexanes
DOI
doi.org/10.1021/ma500042f
Published Date
Mar 10, 2014
Journal
Macromolecules
Volume
47
Issue
6
Pages
1959 - 1965
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