Phase stability in high entropy alloys: Formation of solid-solution phase or amorphous phase

The alloy design for equiatomic multi-component alloys was rationalized by statistically analyzing the atomic size difference, mixing enthalpy, mixing entropy, electronegativity, valence electron concentration among constituent elements in solid solutions forming high entropy alloys and amorphous alloys. Solid solution phases form and only form when the requirements of the atomic size difference, mixing enthalpy and mixing entropy are all met....