Zhong Shao
Sichuan University
Cleavage (embryo)Medicinal chemistryChemistryPolymer chemistryAminationNitroxylAlkoxylationTandemN-fluorobenzenesulfonimideBioactive moleculesMetal freeBond cleavageReagentMetalCopperOrganocatalysisLigand
2Publications
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7Citations
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#1Zhong ShaoH-Index: 1
#2Fang WangH-Index: 3
Last. Ziyuan Li (Sichuan University)H-Index: 11
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1 CitationsSource
#1Qi Miao (Sichuan University)H-Index: 3
#2Zhong Shao (Sichuan University)H-Index: 1
Last. Ziyuan Li (Sichuan University)H-Index: 11
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A TEMPO-catalysed direct amination of arene through C–H bond cleavage employing N-fluorobenzenesulfonimide (NFSI) as the amination reagent in good to excellent yields with broad arene scope in the absence of any metal, ligand or additive is reported. Unlike previous transition metal-catalysed aminations in which high reaction temperatures are usually necessary, this novel reaction at room temperature is the first example of C–H amination with NFSI that is realised via organocatalysis. The probab...
11 CitationsSource