Engineering

Ecology

Biology

Radiative cooling

Emissivity

Materials science

Environmentally friendly

Cellulose

Passive cooling

Scalability

Civil engineering

Computer science

Chemical engineering

Facade

Waste management

Physics

Database

Renewable energy

Optics

Thermal

Process engineering

Environmental science

Composite material

Architectural engineering

Meteorology

Papermaking

Electrical engineering

Chemical Engineering Journal

Passive radiative cooling materials provide coldness without energy consumption for all-day thermal comfort by reflecting solar irradiation and emitting heat into the 3 K universe. However, the conventional radiative cooling materials involve complex multilayer structures and unsustainable polymers, showing the non-recyclable disadvantage, which induces resource waste and environmental issues. Herein, we reported a low-cost, scalable, and eco-friendly radiative cooling material (namely cooling paper), consisting of the delignified, fibrillated cellulose fibers and nano-sized hydroxyapatite (HA) via the mature pulping and papermaking process. The resulting cooled paper can be recycled, and it can be easily deconstructed to harvest cellulose fibers and HA, individually. The recovered source materials can be reused to prepare secondary products that show comparable performance to the original cooling paper, including a high solar reflectance of ∼94% and an infrared emissivity of ∼0.95 in the atmospheric transparency window. Such cooling paper enables superior cooling performance with the temperature drop of 6 ∼ 8.8 °C under directly solar radiation. Based on the EnergyPlus simulation, our cooling paper shows a average cooling energy saving of ∼29 % in buildings across China. The recyclable cooling paper with high cooling capability and scalability, as well as environmental friendliness, shows promising potential for sustainable energy-efficient buildings.

A recyclable, up-scalable and eco-friendly radiative cooling material for all-day sub-ambient comfort