Physics

Organic chemistry

Swelling

Hydrogen

Atmosphere (unit)

Composite material

Pellet

Chemistry

Reducing atmosphere

Metallurgy

Materials science

Volume (thermodynamics)

Pellets

Pelletizing

Thermodynamics

International Journal of Minerals Metallurgy and Materials

Hydrogen-based shaft furnace process is gaining more and more attention due to its low carbon emission, and the reduction behavior of iron bearing burdens significantly affects its operation. In this work, the effects of reduction degree, temperature, and atmosphere on the swelling behavior of pellet has been studied thoroughly under typical hydrogen metallurgy conditions. The results show that the pellets swelled rapidly in the early reduction stage, then reached a maximum reduction swelling index (RSI) at approximately 40% reduction degree. The crystalline transformation of the iron oxides during the reduction process was the main reason of pellets swelling. The RSI increased significantly with increasing temperature in the range of 850–1050°C, the maximum RSI increased from 6.66% to 25.0% in the gas composition of 100% H2. With the temperature increased, the pellets suffered more thermal stress resulting in an increase of the volume. The maximum RSI decreased from 19.78% to 17.35% with the volume proportion of H2 in the atmosphere increased from 55% to 100% at the temperature of 950°C. The metallic iron tended to precipitate in a lamellar structure rather than whiskers. Consequently, the inside of the pellets became regular, so the RSI decreased. Overall, controlling a reasonable temperature and increasing the H2 proportion is an effective way to decrease the RSI of pellets.

Direct reduction swelling behavior of pellets in hydrogen-based shaft furnaces under typical atmospheres