Nuclear chemistry

Sodium

Adsorption

Engineering

Polymer chemistry

Materials science

Bentonite

Itaconic acid

Carboxymethyl cellulose

Safranin

Montmorillonite

Chemical engineering

Langmuir adsorption model

Polymer

Cationic polymerization

Sorption

Organic chemistry

Copolymer

Langmuir

Acrylic acid

Staining

Medicine

Chemistry

Pathology

Environmental Research

Copolymer of acrylic acid (AA) and itaconic acid (IA) grafted onto sodium carboxymethyl cellulose hydrogel (CMC-g-poly (AA-co-IA)) was successfully synthesized as an adsorbent to remove safranin-O from wastewater. The swelling and removal efficiencies of CMC-g-poly (AA-co-IA) were enhanced by increasing IA/AA molar ratio as well as by incorporation of montmorillonite clay nano-sheets (MMT). The surface area of MMT, CMC-g-poly (AA-co-IA), and CMC-g-poly (AA-co-IA) samples was 15.632, 0.61452, and 0.66584 m2/g, respectively, indicating the effectiveness of MMT nano-sheets in improving hydrogel surface area. The maximum removal efficiency of CMC-g-poly (AA-co-IA)/MMT under optimum conditions i.e., pH of 8, initial concentration of 10 mg/L, adsorbent dose of 2 g/L, and contact time of 40 min was ascertained 99.78% using a response surface methodology-central composite design (RSM-CCD). Pseudo-second-order and Langmuir models giving the maximum monolayer adsorption capacity of 18.5185 mg/g and 19.1205 mg/g for CMC-g-poly (AA-co-IA) and CMC-g-poly (AA-co-IA)/MMT samples, respectively are the best-fitted models for kinetic and equilibrium data. Thermodynamically, safranin-O decontamination was spontaneous, exothermic, and entropy decreasing. Moreover, ad (de)sorption behavior study showed that CMC-g-poly (AA-co-IA)/MMT performance was not changed after multiple recovery steps. Therefore, CMC-g-poly (AA-co-IA)/MMT was considered as a highly potential adsorbent for safranin-O removal from wastewater.

Safranin-O cationic dye removal from wastewater using carboxymethyl cellulose-grafted-poly(acrylic acid-co-itaconic acid) nanocomposite hydrogel