Metal

Scaffold

Engineering

Biomedical engineering

Stretchable electronics

Metallurgy

Materials science

Elongation

Ultimate tensile strength

Flexible electronics

In situ

Physical chemistry

Nanotechnology

Organic chemistry

Liquid metal

Electrical resistance and conductance

Electronics

Conductivity

Composite material

Chemistry

Nanofiber

Electrode

Electrical engineering

Electrical conductor

InfoMat

The development of stretchable electronics could enhance novel interface structures to solve the stretchability–conductivity dilemma, which remains a major challenge. Herein, we report a nano‐liquid metal (LM)‐based highly robust stretchable electrode (NHSE) with a self‐adaptable interface that mimics water‐to‐net interaction. Based on the in situ assembly of electrospun elastic nanofiber scaffolds and electrosprayed LM nanoparticles, the NHSE exhibits an extremely low sheet resistance of 52 mΩ sq −1 . It is not only insensitive to a large degree of mechanical stretching (i.e., 350% electrical resistance change upon 570% elongation) but also immune to cyclic deformation (i.e., 5% electrical resistance increases after 330 000 stretching cycles with 100% elongation). These key properties are far superior to those of the state‐of‐the‐art reports. Its robustness and stability are verified under diverse circumstances, including long‐term exposure to air (420 days), cyclic submersion (30 000 times), and resilience against mechanical damages. The combination of conductivity, stretchability, and durability makes the NHSE a promising conductor/electrode solution for flexible/stretchable electronics for applications such as wearable on‐body physiological signal detection, human–machine interaction, and heating e‐skin. image

Ultra‐robust stretchable electrode for e‐skin: In situ assembly using a nanofiber scaffold and liquid metal to mimic water‐to‐net interaction