Quantum mechanics

Catalysis

Engineering

Thermogravimetric analysis

SPARK (programming language)

Metallurgy

Materials science

Mineralogy

Ceramic

Caesium

Plasma

Biochemistry

Computer science

Inorganic chemistry

Chemical engineering

Hydrothermal synthesis

Physical chemistry

Physics

Organic chemistry

Solid-state

Hydrothermal circulation

Zeolite

Spark plasma sintering

Faujasite

Composite material

Sintering

Chemistry

Programming language

Thermal stability

Journal of the European Ceramic Society

Hydrothermal synthesis of NaY-type zeolite was carried out and the effect of temperature on the phase composition, crystal structure, textural characteristics, particle size and morphology, as well as sorption properties to Cs + ions was studied. Solid-state matrices based on NaY zeolite the Faujasite structure containing 26.1 wt% cesium were obtained by spark plasma sintering (SPS) with high values of compressive strength (to 132.9 MPa) and Vickers microhardness to HV~ 698, Fracture toughness (K 1c ) ~ 1.26 MPa m 1/2 . The kinetics of ceramic matrices consolidation, phase composition and morphology using dilatometric studies, XRD, and SEM were studied. The thermogravimetric analysis shown the high thermal stability of the obtained samples up to 1300 °C. The high hydrolytic stability of CsAlSiO 4 ceramic was proven (leaching rate of 2.33 ×10 −8 g·cm − 2 ·day −1 and cesium diffusion coefficient De 1.41 ×10 −13 ), which exceeds the requirements of GOST R 50926–96 and ISO 6961:1982 for solid-state matrices.

Hydrothermal synthesis and spark plasma sintering of NaY zeolite as solid-state matrices for cesium-137 immobilization