Spectroscopy

Quantum mechanics

Catalysis

Dielectric spectroscopy

Composite number

Engineering

Electrochemistry

Materials science

Biochemistry

Computer science

Photoluminescence

Chemical engineering

Band gap

Ternary operation

Physical chemistry

Visible spectrum

Physics

Organic chemistry

Tetracycline Hydrochloride

Degradation (telecommunications)

CZTS

Antibiotics

Electronic engineering

Composite material

Heterojunction

Chemistry

Programming language

Electrode

Tetracycline

Photocatalysis

Optoelectronics

Journal of Alloys and Compounds

A novel CdS/Bi2MoO6/BiOBr successive Z-scheme photocatalyst has been synthesized by a solvothermal-precipitation method. The structure, composition, morphology and optical property of the ternary composite were investigated. The maximum degradation rate of CdS/Bi2MoO6/BiOBr for tetracycline hydrochloride (TC) can reach 94.41% under visible light, while its degradation rate was 10.43, 2.89, and 2.43 times higher than that of pure Bi2MoO6, BiOBr and Bi2MoO6/BiOBr, respectively. Besides, the CdS/Bi2MoO6/BiOBr composite showed stable catalytic performance after three successive reuses. The improved photocatalytic and stability could be ascribed to the extended visible-light absorption capability, effective separation of electron-hole pairs and layered stable structure. Photoluminescence spectroscopy and electrochemical impedance spectroscopy proved that the composite had more efficient charge separation efficiency. The energy band structure and free radical capturing experiments proved that the redox reaction mainly occurred in the conduction band of CdS and the valence band of BiOBr in this composite, so a possible successive Z-scheme heterojunction mechanism is proposed. This work also provides a feasible idea for the treatment of TC in wastewater.

Synthesis and characterization of successive Z-scheme CdS/Bi2MoO6/BiOBr heterojunction photocatalyst with efficient performance for antibiotic degradation