line positions

Journal of Quantitative Spectroscopy & Radiative Transfer

• Frequency comb Fourier transform spectroscopy at 7.8 µm based on a compact difference frequency generation source. • High-precision measurements of the ν 1 fundamental band and the ν 1 + ν 2 – ν 2 hot band of 14 N 2 16 O. • Line positions with uncertainties of the order of 90-600 kHz. We use a Fourier transform spectrometer based on a compact mid-infrared difference frequency generation comb source to perform broadband high-resolution measurements of nitrous oxide, 14 N 2 16 O, and retrieve line center frequencies of the ν 1 fundamental band and the ν 1 + ν 2 – ν 2 hot band. The spectrum spans 90 cm −1 around 1285 cm −1 with a sample point spacing of 3 × 10 −4 cm −1 (9 MHz). We report line positions of 72 lines in the ν 1 fundamental band between P(37) and R(38), and 112 lines in the ν 1 + ν 2 – ν 2 hot band (split into two components with e/f rotationless parity) between P(34) and R(33), with uncertainties in the range of 90-600 kHz. We derive upper state constants of both bands from a fit of the effective ro-vibrational Hamiltonian to the line center positions. For the fundamental band, we observe excellent agreement in the retrieved line positions and upper state constants with those reported in a recent study by AlSaif et al. using a comb-referenced quantum cascade laser [J Quant Spectrosc Radiat Transf, 2018;211:172-178]. We determine the origin of the hot band with precision one order of magnitude better than previous work based on FTIR measurements by Toth [ http://mark4sun.jpl.nasa.gov/n2o.html ], which is the source of the HITRAN2016 data for these bands.

Optical frequency comb Fourier transform spectroscopy of 14N216O at 7.8 µm