Physics

Organic chemistry

Coal

Thermogravimetric analysis

Energy storage

Composite number

Optics

Engineering

Carbon fibers

Composite material

Mineralogy

Power (physics)

Raw material

Inorganic chemistry

Chemistry

Materials science

Raman spectroscopy

Chemical engineering

Anthracite

Thermodynamics

Energy & environment materials

As the limiting factor for an energy storage technique from lab‐scale to industrial‐scale, cost means not only the price of raw materials but also the simplicity of processing technics. In this work, the oxygen functionalized carbon materials were obtained from three representative different metamorphic‐grade coals, that is, lignite, bitumite, anthracite. Oxygen functional groups like quinones, carboxylic anhydrides, and lactones are easier to form near defects according to the thermogravimetric‐mass spectrometry measurements and density functional theory calculation. Considering the highest amount of defects and C=O contained functional groups, the low metamorphic‐grade lignite derived carbon exhibits a reversible capacity of 259.7 mA h g −1 after 50 cycles at 0.03 A g −1 , best among these micron sized coal‐based carbons. The surface active sites contribute highly stable and majority of sodium storage capacity evidenced by in situ Raman spectra and cyclic voltammetry curves at different scan rates. The coal‐based carbon materials in this work offer options for industrial applications of sodium‐ion battery anode materials.

Directional Oxygen Functionalization by Defect in Different Metamorphic‐Grade Coal‐Derived Carbon Materials for Sodium Storage