Organic chemistry

Ring (chemistry)

Reagent

Hypervalent molecule

Catalysis

Medicinal chemistry

Rearrangement reaction

Chemistry

Oxime

Claisen rearrangement

Cyclopropane

Oxidative phosphorylation

Beckmann rearrangement

Iodine

Biochemistry

Sigmatropic reaction

Chemical Communications

We summarize the developments of hypervalent iodine reagents-mediated reactions involving [1,2]-migration, Hofmann rearrangement, Beckmann rearrangement, ring contraction/expansion, [3,3]-sigmatropic/iodonium-Claisen rearrangement and some miscellaneous rearrangements.

Hypervalent iodine reagent-mediated reactions involving rearrangement processes