permeate flux

membrane fouling

nf membranes

membrane bioreactor

nanofiltration nf

water purification

membrane filtration

composite membrane

water permeance

pvdf membrane

ACS Applied Materials & Interfaces

Nanofiltration plays an increasingly large role in many industrial applications, such as water treatment (e.g., desalination, water softening, and fluoride removal) and resource recovery (e.g., alkaline earth metals). Energy consumption and benefits of nanofiltration processes are directly determined by the selectivity of the nanofiltration membranes, which is largely governed by pore-size distribution and Donnan effects. During operation, the separation performance of unmodified nanofiltration membranes will also be impacted (deleteriously) upon unavoidable membrane fouling. Many efforts, therefore, have been directed toward enhancing the selectivity of nanofiltration membranes, which can be classified into membrane fabrication method improvement and process intensification. This review summarizes recent developments in the field and provides guidance for potential future approaches to improve the selectivity of nanofiltration membranes.

Sharpening Nanofiltration: Strategies for Enhanced Membrane Selectivity