Niobium carbide

Quantum mechanics

Chemical physics

Metallurgy

Materials science

Social psychology

Dynamics (music)

Niobium nitride

Carbide

Layer (electronics)

Niobium

Absorption (acoustics)

Acoustics

Wavelength

Photonics

Laser

Physics

Nonlinear system

Nanotechnology

Psychology

Saturable absorption

Optics

Relaxation (psychology)

Internal medicine

Composite material

Medicine

Chemistry

Nitride

Fiber laser

Optoelectronics

Absorption spectroscopy

Ultrashort pulse

Ultrafast laser spectroscopy

Small Methods

As one of the rising 2D materials, niobium‐carbide (Nb 2 C, well‐known as a member of MXene family) has attracted considerable attention owing to its unique physical and chemical properties. In this work, few‐layer Nb 2 C nanosheets (NSs) with large (≈255 nm) and small (≈48 nm) lateral dimensions are obtained via a combination of selective etching and liquid cascade centrifugation. Their relaxation time and photophysics process are systematically investigated by transient absorption spectroscopy, and the size effect is demonstrated by phonon‐bottleneck mechanism. Ultrafast fast relaxation time (37.43 fs) and slow relaxation time (0.5733 ps) are observed due to the symmetric structure and metallicity of Nb 2 C NSs. The nonlinear optical properties of Nb 2 C NSs are studied by Z‐scan technique, and both saturable absorption and reverse‐saturable absorption are observed. According to first principle calculations, these phenomena can be attributed to the special band structure of Nb 2 C near the Fermi level, where two‐photon absorption or multiphoton absorption may occur under the irradiation of long wavelength light. These intriguing results suggest that few‐layer Nb 2 C NSs can be used as building blocks for broadband ultrafast photonics and optoelectronic devices and also hold the potential for breakthrough developments in these fields.

Ultrafast Relaxation Dynamics and Nonlinear Response of Few‐Layer Niobium Carbide MXene