Phase (matter)

Shale gas

Materials science

Mineralogy

Molecular diffusion

Oil shale

Petroleum engineering

Gaseous diffusion

Economics

Thermal diffusivity

Nano-

Knudsen diffusion

Geology

Porosity

Physical chemistry

Paleontology

Thermodynamics

Physics

Organic chemistry

Diffusion

Operations management

Porous medium

Composite material

Tortuosity

Chemistry

Electrode

Metric (unit)

Journal of Petroleum Science and Engineering

Molecular diffusion plays an important role in oil and gas migration in tight shale formations. However, there are insufficient reference data in the literature to specify the diffusion coefficients within porous media. This study aims at calculating diffusion coefficients of shale gas, shale condensate, and shale oil at reservoir conditions with CO2 injection for EOR/EGR. The large nano-confinement effects including large gas-oil capillary pressure and critical property shifts could alter the phase behaviors. This paper estimates the diffusivities of shale fluids in nanometer-scale shale rock from two perspectives: 1) examining the shift of diffusivity caused by nanopore confinement effects from phase change (phase composition and fluid property) perspective, and 2) calculating the effective diffusion coefficient in porous media by incorporating rock intrinsic properties (porosity and tortuosity factor). The tortuosity is obtained by using tortuosity-porosity relations as well as the measured tortuosity of shale from 3D imaging techniques. The results indicated that nano-confinement effects could affect the diffusion coefficient through altering the phase properties, such as phase compositions and densities. Compared to bulk phase diffusivity, the effective diffusion coefficient in porous shale rock is reduced by 102 to 104 times as porosity decreases from 0.1 to 0.03.

Estimating diffusion coefficients of shale oil, gas, and condensate with nano-confinement effect