martensitic

rhcl

parabolic equation

catheters

allergenicity

childhood obesity_114134

uncinate

hastelloy

religious spiritual

ott_129056

Combustion and Flame

Laminar flame speeds of dimethyl ether and dimethoxymethane at pressures from 1 to 5 bar and initial temperatures from 298 to 373 K were determined experimentally using a constant volume spherical vessel and a heat flux burner setup. This study is the first to report dimethoxymethane laminar flame speeds at a pressure higher than 1 bar. Using these experimental data along with data available in the literature, a new kinetic model for the prediction of the oxidation behavior of dimethyl ether and dimethoxymethane in freely propagating and burner stabilized premixed flames , in shock tubes , rapid compression machines, flow reactors, and a jet-stirred reactor has been developed. The experimental results from the present work and literature are interpreted with the help of the derived kinetic model. This newly developed reaction mechanism considers the redox chemistry of NO x to accommodate the influence of the oxygen level on the onset of fuel conversion and interconversion of NO and NO 2 . The current model suggests that an increased O 2 level promotes the HO 2 production, which in turn leads to the formation of OH radicals, which promotes the combustion of the fuel/air mixture under lean conditions. The increase of OH radical concentrations is mainly via the NO/NO 2 interconversion reaction channel, NO+HO 2 =NO 2 +OH, NO 2 +H=NO+OH, CH 3 OCH 3 +NO 2 =CH 3 OCH 2 +HONO , followed by the thermal decomposition of HONO. This work extends the kinetic database and helps to improve the understanding of dimethyl ether and dimethoxymethane combustion behavior. The kinetic model presented in this work can serve as a base model for hydrocarbons and oxygenated fuels higher than C 2 .

A comprehensive kinetic model for dimethyl ether and dimethoxymethane oxidation and NO interaction utilizing experimental laminar flame speed measurements at elevated pressure and temperature