Metal

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Cubane

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Materials science

Phase transition

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Metal-organic framework

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Nickel

Chemistry - A European Journal

An unprecedented spin cluster-based network architecture {[NiII2 (pdaa)(OH)2 (H2 O)]n (H2 pdaa=1,4-phenylene diacetic acid)}, comprising 1D linear chains of NiII ions crosslinked via Ni4 O4 cubanes, forms under hydrothermal conditions; this 3D coordination network exhibits magnetic ordering at 23.9 K as well as a second magnetic ordering process at 2.8 K likely associated with a structural phase transition.

Magnetic Phase Transitions in a Ni <sub>4</sub> O <sub>4</sub> ‐Cubane‐Based Metal–Organic Framework

Magnetic Phase Transitions in a Ni 4 O 4 ‐Cubane‐Based Metal–Organic Framework

Magnetic Phase Transitions in a Ni ₄ O ₄ ‐Cubane‐Based Metal–Organic Framework