Selectivity

Heterogeneous catalysis

Organic chemistry

Hydrocarbon

Composite number

Transition metal

Methanation

Engineering

Catalysis

Carbon fibers

Composite material

Chemistry

Materials science

In situ

Carbon monoxide

Fischer–Tropsch process

Chemical engineering

ChemCatChem

Heterogeneous iron catalysts are active in the hydrogenation of carbon oxides and are widely investigated for the production of long‐chained hydrocarbons according to the Fischer‐Tropsch synthesis. Moreover, high selectivity of light hydrocarbons, such as CH 4 , also occurs strongly depending on reaction conditions and catalyst formulations. As a consequence, Fe catalysts reveal promising methanation activity as referred to the traditional Ni catalysts. Additionally, Fe catalysts also benefit from their low price and toxicological harmlessness. However, the dynamic behavior of iron upon CO 2 hydrogenation is not yet unraveled unambiguously including phase transformations, structural changes and participation of carbon species formed. The present review highlights these complex processes of Fe catalysts with special focus on the methanation of CO 2 . Additionally, different analytical tools useful for ex situ and in situ studies are critically evaluated.

Activity and Structural Changes of Fe‐based Catalysts during CO<sub>2</sub> Hydrogenation towards CH<sub>4</sub> – A Mini Review

Activity and Structural Changes of Fe‐based Catalysts during CO2 Hydrogenation towards CH4 – A Mini Review

Activity and Structural Changes of Fe‐based Catalysts during CO₂ Hydrogenation towards CH₄ – A Mini Review