Ostwald ripening

Engineering

Materials science

Grain growth

Perovskite (structure)

Chemical engineering

Grain boundary

Grain size

Physics

Hysteresis

Nanotechnology

Perovskite solar cell

Microstructure

Condensed matter physics

Solar cell

Composite material

Energy conversion efficiency

Optoelectronics

Photovoltaic system

Electrical engineering

Advanced Materials

As one kind of promising next‐generation photovoltaic devices, perovskite solar cells (PVSCs) have experienced unprecedented rapid growth in device performance over the past few years. However, the practical applications of PVSCs require much improved device long‐term stability and performance, and internal defects and external humidity sensitivity are two key limitation need to be overcome. Here, gadolinium fluoride (GdF 3 ) is added into perovskite precursor as a redox shuttle and growth‐assist; meanwhile, aminobutanol vapor is used for Ostwald ripening in the formation of the perovskite layer. Consequently, a high‐quality perovskite film with large grain size and few grain boundaries is obtained, resulting in the reduction of trap state density and carrier recombination. As a result, a power conversion efficiency of 21.21% is achieved with superior stability and negligible hysteresis.

Suppressing Vacancy Defects and Grain Boundaries via Ostwald Ripening for High‐Performance and Stable Perovskite Solar Cells