Original paper

Ground state chemistry under vibrational strong coupling: dependence of thermodynamic parameters on the Rabi splitting energy

Volume: 9, Issue: 2, Pages: 249 - 255
Published: Nov 29, 2019
Abstract
Vibrational strong coupling (VSC) is currently emerging as a tool to control chemical dynamics. Here we study the impact of strong coupling strength, given by the Rabi splitting energy ( ħ Ω R ), on the thermodynamic parameters associated with the transition state of the desilylation reaction of the model molecule 1-phenyl-2-trimethylsilylacetylene. Under VSC, the enthalpy and entropy of activation determined from the temperature-dependent...
Paper Details
Title
Ground state chemistry under vibrational strong coupling: dependence of thermodynamic parameters on the Rabi splitting energy
Published Date
Nov 29, 2019
Volume
9
Issue
2
Pages
249 - 255
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