Turning on Visible-Light Photocatalytic C−H Oxidation over Metal–Organic Frameworks by Introducing Metal-to-Cluster Charge Transfer

Volume: 141, Issue: 48, Pages: 19110 - 19117
Published: Nov 10, 2019
Abstract
The tailorable structure and electronic structure of metal–organic frameworks (MOFs) greatly facilitate their modulated light harvesting, redox power, and consequently photocatalysis. Herein, a representative MOF, UiO-66, was furnished by installing Fe3+ onto the Zr-oxo clusters, to give Fe-UiO-66, which features extended visible light harvesting, based on metal-to-cluster charge transfer (MCCT). The Fe-UiO-66 with unique electronic structure...
Paper Details
Title
Turning on Visible-Light Photocatalytic C−H Oxidation over Metal–Organic Frameworks by Introducing Metal-to-Cluster Charge Transfer
Published Date
Nov 10, 2019
Volume
141
Issue
48
Pages
19110 - 19117
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