Physics

Geology

Hesperian

Geomorphology

Diagenesis

Lithology

Geochemistry

Impact crater

Noachian

Martian

Sedimentary rock

Mars Exploration Program

Astrobiology

Nature Geoscience

Precipitated minerals, including salts, are primary tracers of atmospheric conditions and water chemistry in lake basins. Ongoing in situ exploration by the Curiosity rover of Hesperian (around 3.3–3.7 Gyr old) sedimentary rocks within Gale crater on Mars has revealed clay-bearing fluvio-lacustrine deposits with sporadic occurrences of sulfate minerals, primarily as late-stage diagenetic veins and concretions. Here we report bulk enrichments, disseminated in the bedrock, of 30–50 wt% calcium sulfate intermittently over about 150 m of stratigraphy, and of 26–36 wt% hydrated magnesium sulfate within a thinner section of strata. We use geochemical analysis, primarily from the ChemCam laser-induced breakdown spectrometer, combined with results from other rover instruments, to characterize the enrichments and their lithology. The deposits are consistent with early diagenetic, pre-compaction salt precipitation from brines concentrated by evaporation, including magnesium sulfate-rich brines from extreme evaporative concentration. This saline interval represents a substantial hydrological perturbation of the lake basin, which may reflect variations in Mars’ obliquity and orbital parameters. Our findings support stepwise changes in Martian climate during the Hesperian, leading to more arid and sulfate-dominated environments as previously inferred from orbital observations. Brines from evaporation of a lake in Gale crater on Mars are inferred from bulk enrichments of Ca- and Mg-sulfates in Hesperian sedimentary rocks, identified by geochemical analyses and observations by NASA’s rover Curiosity.

An interval of high salinity in ancient Gale crater lake on Mars