Geology

Climate change

Meteorology

Stratosphere

Organic chemistry

Greenhouse gas

Biology

Atmospheric sciences

Climate model

Copolymer

Geography

Chemistry

Ecology

Tropospheric ozone

Climatology

Isoprene

Troposphere

Environmental science

Ozone

Polymer

Current Pollution Reports

Tropospheric ozone is a key air pollutant and greenhouse gas. Its fate strongly depends on meteorological conditions and therefore subject to climate change influences. Such dependences through biogenic, chemical, and dynamic processes on different spatiotemporal scales have been unraveled from observations and modeling studies. In this process-oriented review, we summarize three dominant pathways of meteorological and climatic impacts on tropospheric ozone and present their recent progress. The three pathways are influences through changes in the natural precursor emissions, the kinetics and partitioning of chemistry and deposition, and the transport of ozone and its precursors. Tropospheric ozone levels have shown significant global or regional responses to meteorological/climatic changes (e.g., changes in the Brewer-Dobson Circulation, the Hadley Circulation, and El Niño–Southern Oscillation) and can be explained through the conjunction of these pathways. Most recent model projections predict that future climate will increase surface ozone in polluted regions and decrease ozone at a global scale due to stronger ozone chemical loss. However, uncertainties in climate-ozone responses and limitations in model capability still challenge the magnitude and even the sign of such projections. We highlight the rising importance of future increase of stratosphere-troposphere exchange in modulating tropospheric ozone that may largely compensate the predicted chemical loss of tropospheric ozone burden. We also highlight that uncertainties in isoprene chemistry, biogenic emissions in changing CO2 levels and vegetation, and interactions between ozone and vegetation may largely affect the surface ozone response to climate change. Future research and model improvements are required to fill these gaps.

Meteorology and Climate Influences on Tropospheric Ozone: a Review of Natural Sources, Chemistry, and Transport Patterns