Rational Study of DBU Salts for the CO2 Insertion into Epoxides for the Synthesis of Cyclic Carbonates
Volume: 7, Issue: 12, Pages: 10633 - 10640
Published: May 14, 2019
Abstract
A series of alkylated or protonated bicyclic amidine or DBU organocatalysts were investigated for the synthesis of cyclic carbonates from CO2 and epoxides. The impact of the counteranion was examined in protonated samples where salts featuring halides displayed superior activity as a consequence of the nucleophilicity of the halide. The simple iodide salt of DBU ([HDBU]I) displayed the highest activity for the carboxylation of styrene oxide at...
Paper Details
Title
Rational Study of DBU Salts for the CO2 Insertion into Epoxides for the Synthesis of Cyclic Carbonates
Published Date
May 14, 2019
Volume
7
Issue
12
Pages
10633 - 10640
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