Annealing (glass)

Quantum mechanics

Metallurgy

Materials science

Chromatography

Coercivity

Nuclear physics

Grain boundary diffusion coefficient

Grain growth

Neodymium magnet

Grain boundary

Thermodynamics

Physics

Diffusion

Microstructure

Condensed matter physics

Analytical Chemistry (journal)

Crystallography

Chemistry

Dysprosium

Magnet

Acta Materialia

Dy distributions in Dy-free and Dy-containing NdFeB sintered magnets in the course of the Dy-vapor grain boundary diffusion (GBD) process have been investigated in order to understand the origin of the high coercivity of 3.0 T that is reachable only when the initial magnet is alloyed with Dy. We have discovered the formation of a secondary Dy-rich shell within the well-known primary Dy-rich shell, which is a key contributor to the 3.0 T coercivity. The coercivity increment of the Dy-containing magnet after the GBD treatment was only 0.08 T, much lower than 0.87 T for the Dy-free magnet; however, it was substantially enhanced by a post-diffusion annealing. Compared to the Dy-free magnet, a larger amount of Dy atoms were diffused from the Nd-rich grain boundary (GB) phase to the primary Dy-rich shell in the Dy-containing magnet after the annealing, resulting in the formation of a secondary Dy-rich shell with a higher Dy-concentration at the GB phase/secondary shell interfaces.

Microstructure and coercivity of grain boundary diffusion processed Dy-free and Dy-containing Nd Fe B sintered magnets