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Original paper

Site-Selective Functionalization of Linear Diterpenoids through U-Shaped Folding in a Confined Artificial Cavity

Volume: 141, Issue: 13, Pages: 5112 - 5115
Published: Mar 15, 2019
Abstract
Even flexible linear substrates are conformationally fixed within the hydrophobic confined cavities of enzymes. This enables preorganization of the substrates and their positioning in close proximity to the active center to facilitate stereo- and site-selective reactions. Here, we demonstrate the site-selective electrophilic addition of linear diterpenoids within a self-assembled coordination cage. The reactions proceed through folding of the...
Paper Details
Title
Site-Selective Functionalization of Linear Diterpenoids through U-Shaped Folding in a Confined Artificial Cavity
Published Date
Mar 15, 2019
Volume
141
Issue
13
Pages
5112 - 5115
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