Quantum mechanics

Materials science

Refractive index

Modulation (music)

Acoustics

Silicon

Electronic circuit

Barium titanate

Photonics

Laser

Physics

Dielectric

Optics

Silicon photonics

Pockels effect

Optoelectronics

Ultrashort pulse

Nature Materials

The electro-optical Pockels effect is an essential nonlinear effect used in many applications. The ultrafast modulation of the refractive index is, for example, crucial to optical modulators in photonic circuits. Silicon has emerged as a platform for integrating such compact circuits, but a strong Pockels effect is not available on silicon platforms. Here, we demonstrate a large electro-optical response in silicon photonic devices using barium titanate. We verify the Pockels effect to be the physical origin of the response, with r42 = 923 pm V−1, by confirming key signatures of the Pockels effect in ferroelectrics: the electro-optic response exhibits a crystalline anisotropy, remains strong at high frequencies, and shows hysteresis on changing the electric field. We prove that the Pockels effect remains strong even in nanoscale devices, and show as a practical example data modulation up to 50 Gbit s−1. We foresee that our work will enable novel device concepts with an application area largely extending beyond communication technologies. Electro-optic modulators based on epitaxial barium titanate (BTO) integrated on silicon exhibit speeds up to 50 Gbit s–1 while the Pockels coefficient of the BTO film is found to be approaching the bulk value.

Large Pockels effect in micro- and nanostructured barium titanate integrated on silicon