Quantum dot

Nanotechnology

Tafel equation

Electrode

Organic chemistry

Electrophoretic deposition

Cyclic voltammetry

Coating

Heterojunction

Analytical Chemistry (journal)

Engineering

Transmission electron microscopy

Physical chemistry

Composite material

Chemistry

Metallurgy

Materials science

Scanning electron microscope

Linear sweep voltammetry

Oxide

Tin oxide

Chemical vapor deposition

Chemical engineering

Optoelectronics

Electrochemistry

ACS Sustainable Chemistry & Engineering

A facile, low-cost, and straightforward procedure was developed for vertical deposition of MoS2 quantum dots (QDs)/nanoflakes (NFs) on fluorine-doped tin oxide (FTO) substrate without any binder. Bulk MoS2 powder was exfoliated in a bath sonicator followed by tip sonicator inside a water–ethanol (0.5/0.5 volume ratio) solution. The obtained MoS2 QDs/NFs are deposited on FTO substrate via a simple electrophoretic technique which resulted in vertical deposition of MoS2 nanoflakes. Field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM) confirmed the formation of MoS2 nanoflakes with thickness of ∼20 nm and lateral dimension of ∼400 nm; transmission electron microscopy (TEM) and AFM analysis revealed that many single- or two-layer MoS2 quantum dots exist with lateral size of ∼5 nm on average on the basal plains of MoS2 nanoflakes. Electrochemical measurements indicated that the vertical MoS2 QDs/NFs/FTO electrode has a Tafel slope of 74 mV/decade and charge transport resistance (Rct) of 16 Ω which is ∼1.9 and 2.7 times smaller than the Tafel slope and Rct of the nonvertical MoS2 NFs/FTO electrode, respectively. This unique morphology exhibited excellent stability for the electrocatalytic hydrogen evolution reaction (HER) after a repeating linear sweep voltammetry (LSV) test for 1000 cycles.

Vertically Aligned MoS<sub>2</sub> Quantum Dots/Nanoflakes Heterostructure: Facile Deposition with Excellent Performance toward Hydrogen Evolution Reaction

Vertically Aligned MoS2 Quantum Dots/Nanoflakes Heterostructure: Facile Deposition with Excellent Performance toward Hydrogen Evolution Reaction

Vertically Aligned MoS₂ Quantum Dots/Nanoflakes Heterostructure: Facile Deposition with Excellent Performance toward Hydrogen Evolution Reaction