Metal

Catalysis

Algorithm

Composite number

Metallurgy

Materials science

Electrophile

Transition metal

Computer science

Carbonylation

Carbon monoxide

Carbon fibers

Base metal

Combinatorial chemistry

Organic chemistry

Mathematics

Nucleophile

Mathematical analysis

Chemistry

Welding

Base (topology)

Chemical Reviews

The main contributions in the field of first-row transition-metal-catalyzed (base-metal-catalyzed) carbonylative transformations have been summarized and discussed. The contents have been divided according to the electrophiles applied, followed by the different types of nucleophiles. Their reaction mechanisms and applications have been emphatically discussed.

First-Row Transition-Metal-Catalyzed Carbonylative Transformations of Carbon Electrophiles