Physics

Electrode

Organic chemistry

Sintering

Crystallography

Analytical Chemistry (journal)

Endocrinology

Engineering

Crystallite

Physical chemistry

Power (physics)

Ionic bonding

Inorganic chemistry

Chemistry

Metallurgy

Materials science

Programming language

Lithium (medication)

Computer science

Battery (electricity)

Quantum mechanics

Lithium carbonate

Electrolyte

Crystal (programming language)

Chemical engineering

Chromatography

Electrochemistry

Medicine

Single crystal

Journal of The Electrochemical Society

Single crystal LiNi0.5Mn0.3Co0.2O2 (NMC532) was shown to have superior stability at high voltages and elevated temperatures compared to conventional polycrystalline NMC532 by the authors. Conventional LiNi0.6Mn0.2Co0.2O2 (NMC622) usually offers more capacity than NMC532 when charged to the same upper cutoff voltage so NMC622 is attractive. It is expected that single crystal NMC622 could also provide better performance than typical polycrystalline NMC622 materials. This work explores the synthesis of single crystal LiNi0.6Mn0.2Co0.2O2 and preferred synthesis conditions were found. A washing and reheating method was used to remove residual lithium carbonate after sintering. The synthesized single crystal NMC622 material worked poorly after the washing-heating treatment without the use of electrolyte additives in the electrolyte. However, with selected additives, single crystal cells outperformed the polycrystalline reference cells in cycling tests. It is our opinion that single crystal NMC622 has a bright future in the Li-ion battery field.

Synthesis of Single Crystal LiNi0.6Mn0.2Co0.2O2with Enhanced Electrochemical Performance for Lithium Ion Batteries