Nanotechnology

Reflection loss

Composite number

Absorption (acoustics)

Dielectric

Ceramic

Composite material

Metallurgy

Materials science

Graphite

Oxide

Graphene

Microwave

Computer science

Chemical vapor deposition

Optoelectronics

Telecommunications

Dielectric loss

Advanced Functional Materials

High‐performance graphene microwave absorption materials are highly desirable in daily life and some extreme situations. A simple technique for the direct growth of graphene as absorption fillers in wave‐transmitting matrices is of paramount importance to bring it to real‐world application. Herein, a simple chemical vapor deposition (CVD) route for the direct growth of edge‐rich graphene (ERG) with tailored structures and tunable dielectric properties in porous Si 3 N 4 ceramics using only methyl alcohol (CH 3 OH) as precursor is reported. The large O/C atomic ratio of CH 3 OH helps to build a mild oxidizing atmosphere and leads to a unique structure featuring open graphite nanosteps and freestanding nanoplanes, endowing the ERG/Si 3 N 4 hybrid with an appropriate balance between good impedance matching and strong loss capacity. Accordingly, the prepared materials exhibit superior electromagnetic wave absorption, far surpassing that of traditional CVD graphene and reduced graphene oxide‐based materials, achieving an effective absorption bandwidth of 4.2 GHz covering the entire X band, with a thickness of 3.75 mm and a negligibly low loading content of absorbents. The results provide new insights for developing novel microwave absorption materials with strong reflection loss and wide absorption frequency range.

Direct Growth of Edge‐Rich Graphene with Tunable Dielectric Properties in Porous Si<sub>3</sub>N<sub>4</sub> Ceramic for Broadband High‐Performance Microwave Absorption

Direct Growth of Edge‐Rich Graphene with Tunable Dielectric Properties in Porous Si3N4 Ceramic for Broadband High‐Performance Microwave Absorption

Direct Growth of Edge‐Rich Graphene with Tunable Dielectric Properties in Porous Si₃N₄ Ceramic for Broadband High‐Performance Microwave Absorption