Organic chemistry

Absorption (acoustics)

Amine gas treating

Engineering

Composite material

Flue gas

Inorganic chemistry

Chemistry

Materials science

Solvent

Mass transfer

Triethylenetetramine

Chemical engineering

Chromatography

Environmental Science & Technology

The main issue related to the deployment of the amine-based absorption process for CO2 capture from flue gas is its intensive energy penalty. Therefore, this study screened a novel biphasic solvent, comprising a primary amine e.g., triethylenetetramine (TETA) and a tertiary amine e.g., N,N-dimethylcyclohexylamine (DMCA), to reduce the energy consumption. The TETA-DMCA blend exhibited high cyclic capacity of CO2 absorption, favorable phase separation behavior, and low regeneration heat. Kinetic analysis showed that the gas- and liquid-side mass transfer resistances were comparable in the lean solution of TETA-DMCA at 40 °C, whereas the liquid-side mass transfer resistance became dominant in the rich solution. The rate of CO2 absorption into TETA-DMCA (4 M, 1:3) solution was comparable to 5 M benchmark monoethanolamine (MEA) solution. Based on a preliminary estimation, the regeneration heat with TETA-DMCA could be reduced by approximately 40% compared with that of MEA. 13C NMR analysis revealed that the CO2 absorption into TETA-DMCA was initiated by the reaction between CO2 and TETA via the zwitterion mechanism, and DMCA served as a CO2 sinker to regenerate TETA, resulting in the transfer of DMCA from the upper to lower phase. The proposed TETA-DMCA solvent may be a suitable candidate for CO2 capture.

Kinetics, Thermodynamics, and Mechanism of a Novel Biphasic Solvent for CO<sub>2</sub> Capture from Flue Gas

Kinetics, Thermodynamics, and Mechanism of a Novel Biphasic Solvent for CO2 Capture from Flue Gas

Kinetics, Thermodynamics, and Mechanism of a Novel Biphasic Solvent for CO₂ Capture from Flue Gas