Original paper
Implications of Occupational Disorder on Ion Mobility in Li4Ti5O12 Battery Materials
Abstract
Lithium–titanium-oxide (Li4Ti5O12, LTO) is unique among battery materials due to its exceptional cyclability and high rate capability. This performance is believed to derive at least partly from the occupational disorder introduced via mixed Li/Ti occupancy in the LTO spinel-like structure. We explore the vast configuration space accessible during high-temperature LTO synthesis by Monte Carlo sampling and indeed find lowest-energy structures to...
Paper Details
Title
Implications of Occupational Disorder on Ion Mobility in Li4Ti5O12 Battery Materials
Published Date
May 17, 2017
Journal
Volume
17
Issue
6
Pages
3884 - 3888