Hydronium

Metal

Protonation

Center (category theory)

Molecule

Computer science

Inorganic chemistry

Organic chemistry

Cluster (spacecraft)

Water cluster

Crystallography

Cobalt

Chemistry

Programming language

Hydrogen bond

Journal of the American Chemical Society

A large protonated water cluster, H+(H2O)27, has been trapped and stabilized within the well-modulated cavity of a 3D metal−organic framework formed by cobalt(II) and 4,4‘-bipyridine-N,N‘-dioxide with a globular Keggin structure [PW12O4]3- anion as template. The structurally characterized protonated water cluster might comprise a (H2O)26 shell with Oh symmetry and a monowater core within the center which is suggested to be a hydronium ion with the Eigen model.

A Large Protonated Water Cluster H+(H2O)27 in a 3D Metal−Organic Framework